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Silly question, what is the message in the log as to why it doesn't post. I have seen where someone enters a blank line in the billing and then the BI fails to post.
I then look at the back and if I see a $0 line with no company I delete that one line in SQL.
This could also be handled in initialize mode in journal entry but I prefer SQL.
Of course your issue would be something completely different and the actual error from the log might shed some light onto the root cause.